- •Contents
- •1.1 Introduction
- •1.2 Selection of dental materials
- •1.3 Evaluation of materials
- •2.1 Introduction
- •2.2 Mechanical properties
- •2.3 Rheological properties
- •2.4 Thermal properties
- •2.5 Adhesion
- •2.6 Miscellaneous physical properties
- •2.7 Chemical properties
- •2.8 Biological properties
- •2.9 Suggested further reading
- •3.1 Introduction
- •3.2 Requirements of dental cast materials
- •3.3 Composition
- •3.4 Manipulation and setting characteristics
- •3.5 Properties of the set material
- •3.6 Applications
- •3.7 Advantages and disadvantages
- •3.8 Suggested further reading
- •4.1 Introduction
- •4.2 Requirements of wax-pattern materials
- •4.3 Composition of waxes
- •4.4 Properties of dental waxes
- •4.5 Applications
- •4.6 Suggested further reading
- •5.1 Introduction
- •5.2 Requirements of investments for alloy casting procedures
- •5.3 Available materials
- •5.4 Properties of investment materials
- •5.5 Applications
- •5.6 Suggested further reading
- •6.1 Introduction
- •6.2 Structure and properties of metals
- •6.3 Structure and properties of alloys
- •6.4 Cooling curves
- •6.5 Phase diagrams
- •6.6 Suggested further reading
- •7.1 Introduction
- •7.2 Pure gold fillings (cohesive gold)
- •7.3 Traditional casting gold alloys
- •7.4 Hardening heat treatments (theoretical considerations)
- •7.5 Heat treatments (practical considerations)
- •7.6 Alloys with noble metal content of at least 25% but less than 75%
- •7.7 Soldering and brazing materials for noble metals
- •7.8 Noble alloys for metal-bonded ceramic restorations
- •7.9 Biocompatibility
- •7.10 Suggested further reading
- •8.1 Introduction
- •8.2 Composition
- •8.3 Manipulation of base metal casting alloys
- •8.4 Properties
- •8.5 Comparison with casting gold alloys
- •8.6 Biocompatibility
- •8.7 Metals and alloys for implants
- •8.8 Suggested further reading
- •9.1 Introduction
- •9.2 Investment mould
- •9.3 Casting machines
- •9.4 Faults in castings
- •9.5 Suggested further reading
- •10.1 Introduction
- •10.2 Steel
- •10.3 Stainless steel
- •10.4 Stainless steel denture bases
- •10.5 Wires
- •10.6 Suggested further reading
- •11.1 Introduction
- •11.2 Composition of traditional dental porcelain
- •11.3 Compaction and firing
- •11.4 Properties of porcelain
- •11.5 Alumina inserts and aluminous porcelain
- •11.6 Sintered alumina core ceramics
- •11.7 Injection moulded and pressed ceramics
- •11.8 Cast glass and polycrystalline ceramics
- •11.9 CAD–CAM restorations
- •11.10 Porcelain veneers
- •11.11 Porcelain fused to metal (PFM)
- •11.12 Capillary technology
- •11.13 Bonded platinum foil
- •11.14 Suggested further reading
- •12.1 Introduction
- •12.2 Polymerisation
- •12.3 Physical changes occurring during polymerisation
- •12.4 Structure and properties
- •12.5 Methods of fabricating polymers
- •12.6 Suggested further reading
- •13.1 Introduction
- •13.2 Requirements of denture base polymers
- •13.3 Acrylic denture base materials
- •13.4 Modified acrylic materials
- •13.5 Alternative polymers
- •13.6 Suggested further reading
- •14.1 Introduction
- •14.2 Hard reline materials
- •14.3 Tissue conditioners
- •14.4 Temporary soft lining materials
- •14.5 Permanent soft lining materials
- •14.6 Self-administered relining materials
- •14.7 Suggested further reading
- •15.1 Introduction
- •15.2 Requirements
- •15.3 Available materials
- •15.4 Properties
- •15.5 Suggested further reading
- •16.1 Introduction
- •16.2 Classification of impression materials
- •16.3 Requirements
- •16.4 Clinical considerations
- •16.5 Suggested further reading
- •17.1 Introduction
- •17.2 Impression plaster
- •17.3 Impression compound
- •17.4 Impression waxes
- •18.1 Introduction
- •18.2 Reversible hydrocolloids (agar)
- •18.3 Irreversible hydrocolloids (alginates)
- •18.5 Modified alginates
- •18.6 Suggested further reading
- •19.1 Introduction
- •19.2 Polysulphides
- •19.3 Silicone rubbers (condensation curing)
- •19.4 Silicone rubbers (addition curing)
- •19.5 Polyethers
- •19.6 Comparison of the properties of elastomers
- •19.7 Suggested further reading
- •20.1 Introduction
- •20.2 Appearance
- •20.3 Rheological properties and setting characteristics
- •20.4 Chemical properties
- •20.5 Thermal properties
- •20.6 Mechanical properties
- •20.7 Adhesion
- •20.8 Biological properties
- •20.9 Historical
- •21.1 Introduction
- •21.2 Composition
- •21.3 Setting reactions
- •21.4 Properties
- •21.6 Manipulative variables
- •21.7 Suggested further reading
- •22.1 Introduction
- •22.2 Acrylic resins
- •22.3 Composite materials – introduction
- •22.4 Classification and composition of composites
- •22.5 Properties of composites
- •22.6 Fibre reinforcement of composite structures
- •22.7 Clinical handling notes for composites
- •22.8 Applications of composites
- •22.9 Suggested further reading
- •23.1 Introduction
- •23.2 Acid-etch systems for bonding to enamel
- •23.3 Applications of the acid-etch technique
- •23.4 Bonding to dentine – background
- •23.5 Dentine conditioning – the smear layer
- •23.6 Priming and bonding
- •23.7 Current concepts in dentine bonding – the hybrid layer
- •23.8 Classification of dentine bonding systems
- •23.9 Bonding to alloys, amalgam and ceramics
- •23.10 Bond strength and leakage measurements
- •23.11 Polymerizable luting agents
- •23.12 Suggested further reading
- •24.1 Introduction
- •24.2 Composition
- •24.3 Setting reaction
- •24.4 Properties
- •24.5 Cermets
- •24.6 Applications and clinical handling notes
- •24.7 Suggested further reading
- •25.1 Introduction
- •25.2 Composition and classification
- •25.3 Setting characteristics
- •25.4 Dimensional change and dimensional stability
- •25.5 Mechanical properties
- •25.6 Adhesive characteristics
- •25.7 Fluoride release
- •25.8 Clinical handling notes
- •25.9 Suggested further reading
- •26.1 Introduction
- •26.2 Requirements
- •26.3 Available materials
- •26.4 Properties
- •27.1 Introduction
- •27.2 Requirements of cavity lining materials
- •27.3 Requirements of Iuting materials
- •27.4 Requirements of endodontic cements
- •27.5 Requirements of orthodontic cements
- •27.6 Suggested further reading
- •28.1 Introduction
- •28.2 Zinc phosphate cements
- •28.3 Silicophosphate cements
- •28.4 Copper cements
- •28.5 Suggested further reading
- •29.1 Introduction
- •29.2 Zinc oxide/eugenol cements
- •29.3 Ortho-ethoxybenzoic acid (EBA) cements
- •29.4 Calcium hydroxide cements
- •29.5 Suggested further reading
- •30.1 Introduction
- •30.2 Polycarboxylate cements
- •30.3 Glass ionomer cements
- •30.4 Resin-modified glass ionomers and compomers
- •30.5 Suggested further reading
- •31.1 Introduction
- •31.2 Irrigants and lubricants
- •31.3 Intra-canal medicaments
- •31.4 Endodontic obturation materials
- •31.5 Historical materials
- •31.6 Contemporary materials
- •31.7 Clinical handling
- •31.8 Suggested further reading
- •Appendix 1
- •Index
Waxes 45
and then replaced and the process repeated until it is warmed throughout. At this stage the softened material can be kneaded before pressing into the prepared cavity.
Inlay waxes are also used widely in the dental laboratory to prepare casting patterns for metallic restorations, either crowns or bridges. The first layer of wax is applied to a die either by adapting a softened thin sheet of wax or using a hot dipping technique. The wax pattern is then developed using a wax-additive technique in which molten wax is applied to the die of the tooth to rebuild
gradually the form of the tooth. Pre-formed resin components are available to facilitate the manufacture of patterns for bridge pontics.
4.6 Suggested further reading
Craig, R.G., Eick, J.D. & Peyton, F.A. (1965) The properties of natural waxes used in dentistry. J. Dent. Res. 44, 1308.
Warth, A.H. (1956) The Chemistry and Technology of Waxes. Von Nostrand Reinhold, New York.
Chapter 5
Investments and Refractory Dies
5.1 Introduction
Following the production of a wax pattern by either the direct or indirect method (Chapter 4), the next stage in many dental procedures involves the investment of the pattern to form a mould. A sprue is attached to the pattern and the assemblage is located in a casting ring (Fig. 5.1). Investment material is poured around the wax pattern whilst still in a fluid state. When the investment sets hard, the wax and sprue former are removed by softening and/or burning out to leave a mould which can be filled with an alloy or ceramic using a casting technique.
In the case of acrylic denture production the base-plate wax is invested in a two-part split mould using dental plaster or stone as the investment. Following removal of the wax the resulting mould is filled with acrylic resin.
The investment mould used for casting alloys and some castable ceramics needs to be constructed from a material which retains its integrity at the casting temperature. Unmodified dental plasters or stones are not suitable for this purpose.
A group of materials which are closely related to the investment materials are the refractory die materials. These products are used for making dies on which ceramic restorations (e.g. porcelain crowns) are constructed. As for the investments used in casting, a prerequisite of the refractory die materials is an ability to retain their structural integrity at the temperatures used to fire ceramics.
Phosphate-bonded die materials are most commonly used for the construction of refractory dies and since these are similar to phosphate bonded investments they will be covered in that section.
5.2 Requirements of investments for alloy casting procedures
The investment material forms the mould into which an alloy will be cast and it therefore follows that the accuracy of the casting can be no better than the accuracy of the mould.
The investment should be capable of reproducing the shape, size and detail recorded in the wax pattern. Since casting is carried out at very high temperatures, often in excess of 1000ºC, the investment mould should be capable of maintaining its shape and integrity at these elevated temperatures. In addition, the investment should have a sufficiently high value of compressive strength at the casting temperature so that it can withstand the stresses set up when the molten metal enters the mould.
Alloy castings undergo considerable contraction when cooling from the casting temperature to room temperature. Such contraction may result in a casting with a very poor fit, for example a simple class I inlay would be loose fitting, whereas a crown would be too small and short at the margin. One function of the investment mould is to compensate for this casting shrinkage. This is generally achieved by a combination of setting expansion during the hardening of the investment mould and thermal expansion during the heating of the mould to the casting temperature.
The main factors involved in the selection of investment material are the casting temperature to be used and the type of alloy to be cast. Some gold alloys are cast at relatively low casting temperatures of around 900ºC whilst some chromium alloys require casting temperatures of around 1450ºC.
46
Investments and Refractory Dies |
47 |
|
|
The investment which is best able to retain its integrity at the casting temperature and able to provide the necessary compensation for casting shrinkage is chosen.
5.3 Available materials
Investment materials consist of a mixture of a refractory material, normally silica, which is capable of withstanding very high temperatures without degradation, and a binder which binds the refractory particles together. The nature of the binder characterises the material.
There are three main groups of investment material in common use. They are referred to as gypsum-bonded, silica-bonded or phosphatebonded.
Wax |
Casting |
pattern |
ring |
|
Investment |
|
material |
Sprue |
|
former |
|
Fig. 5.1 Diagram illustrating how an investment mould is constructed from a wax pattern.
Gypsum-bonded materials
These materials are supplied as powders which are mixed with water and are composed of a mixture of silica (SiO2) and calcium sulphate hemihydrate (gypsum product) together with other minor components including powdered graphite or powdered copper and various modifiers to control setting time.
Silica is a refractory material which adequately withstands the temperatures used during casting. It is available in three allotropic forms – quartz, cristobalite and tridymite – which are all chemically identical but differ slightly in crystalline form. Quartz and cristobalite are used extensively in investments. In addition to imparting the necessary refractory properties to the investment, the silica is responsible for producing much of the expansion which is necessary to compensate for the casting shrinkage of the alloy. The expansion is accomplished by a combination of simple thermal expansion coupled with a crystalline inversion which results in a significant expansion. Quartz undergoes inversion at a temperature of 575ºC from the so-called ‘low’ form or α-quartz to the so-called ‘high’ form or β-quartz. For cristobalite, conversion from the low to the high form occurs at a lower temperature of around 210ºC. The expansion is probably due to a straightening of chemical bonds to form a less dense crystal structure as illustrated in Fig. 5.2. The change is reversible and both quartz and cristobalite revert back to the low form on cooling. The overall thermal expansion and inversion expansion of materials containing cristobalite is greater than those containing quartz as illustrated in Fig. 5.3.
The calcium sulphate hemihydrate is an essential component since it reacts with water to form calcium sulphate dihydrate (gypsum) which
Fig. 5.2 Bond straightening during ‘inversion’ of quartz at 575°C. (a) More dense structure existing below 575°C. (b) Less dense structure existing above 575°C.
48 Chapter 5
Fig. 5.3 Linear expansion versus temperature curves for two types of investment. (a) Containing quartz.
(b) Containing crystobalite.
effectively binds together the refractory silica. The chemistry of setting and important properties of gypsum products are dealt with in Chapter 3. The setting expansion of the calcium sulphate dihydrate, when mixed with water, is used to partially compensate for the shrinkage of the alloy which occurs on casting. Further compensation can be achieved by employing the hygroscopic setting expansion which occurs if the investment mould is placed into water at the initial set stage. The latter method is known as the water immersion hygroscopic expansion technique and can result in an expansion of five times the normal setting expansion. Another method is the water added technique in which a measured volume of water is placed on the upper surface of the investment material within the casting ring. This produces a more readily controlled expansion. Hygroscopic expansion is further encouraged by lining the casting ring with a layer of damp asbestos which is able to feed water to a large surface area of the investment mould. The latter technique is routinely employed even when no attempt is made to maximize hygroscopic expansion by immersing in water or adding water.
The mechanism of hygroscopic expansion is not fully understood. However, it may be envisaged that water is attracted between crystals by capillary action and that the extra separation of particles causes an expansion. The magnitude of the hygroscopic setting expansion which occurs with
gypsum bonded investments is greater than that which occurs with gypsum model and die materials.
Gypsum alone is not satisfactory as an investment for alloy casting since it contracts on heating as water is lost and fractures before reaching the casting temperature. The magnitude of the contraction, which occurs rapidly above 320ºC, is significantly reduced in investment materials by the incorporation of sodium chloride and boric acid.
Three types of gypsum bonded investments can be identified as follows:
Type 1 thermal expansion type; for casting inlays and crowns.
Type 2 hygroscopic expansion type; for casting inlays and crowns.
Type 3 for casting complete and partial dentures.
The ISO Standard for gypsum bonded investments allows individual products to be described by more than one of the above. Hence, materials may be both type 1 and type 3 but must satisfy the most stringent of the requirements outlined in the two standards. Interestingly, the ISO Standard describes all of these materials as ‘Dental gypsumbonded casting investments for gold alloys’, implying that they are suitable only for a limited range of alloys. This is confirmed by a consideration of their properties (Section 5.4).