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Crystallographic point group

In crystallography, a crystallographic point group is a set of symmetry operations, like rotations or reflections, that leave a central point fixed while moving other directions and faces of the crystal to the positions of features of the same kind. For a true crystal (as opposed to a quasicrystal), the group must also be consistent with maintenance of the three-dimensional translational symmetry that defines crystallinity. The macroscopic properties of a crystal would look exactly the same before and after any of the operations in its point group. In the classification of crystals, each point group is also known as a crystal class.

There are infinitely many three-dimensional point groups; However, the crystallographic restriction of the infinite families of general point groups results in there being only 32 crystallographic point groups. These 32 point groups are one-and-the same as the 32 types of morphological (external) crystalline symmetries derived in 1830 by Johann Friedrich Christian Hessel from a consideration of observed crystal forms.

The point group of a crystal, among other things, determines directional variation of the physical properties that arise from its structure, including optical properties such as whether it is birefringent, or whether it shows the Pockels effect.

Notation

The point groups are denoted by their component symmetries. There are a few standard notations used by crystallographers, mineralogists, and physicists.

For the correspondence of the two systems below, see crystal system.

[Edit]Schoenflies notation

Main article: Schoenflies notation

For more details on this topic, see Point groups in three dimensions.

In Schoenflies notation, point groups are denoted by a letter symbol with a subscript. The symbols used in crystallography mean the following:

  • Cn (for cyclic) indicates that the group has an n-fold rotation axis. Cnh is Cn with the addition of a mirror (reflection) plane perpendicular to the axis of rotation. Cnv is Cn with the addition of a mirror plane parallel to the axis of rotation.

  • S2n (for Spiegel, German for mirror) denotes a group that contains only a 2n-fold rotation-reflection axis.

  • Dn (for dihedral, or two-sided) indicates that the group has an n-fold rotation axis plus n twofold axes perpendicular to that axis. Dnh has, in addition, a mirror plane perpendicular to the n-fold axis. Dnd has, in addition to the elements of Dn, mirror planes parallel to the n-fold axis.

  • The letter T (for tetrahedron) indicates that the group has the symmetry of a tetrahedron. Td includes improper rotation operations, T excludes improper rotation operations, and Th is T with the addition of an inversion.

  • The letter O (for octahedron) indicates that the group has the symmetry of an octahedron (or cube), with (Oh) or without (O) improper operations (those that change handedness).

Due to the crystallographic restriction theorem, n = 1, 2, 3, 4, or 6 in 2- or 3-dimensional space.

n

1

2

3

4

6

Cn

C1

C2

C3

C4

C6

Cnv

C1v=C1h

C2v

C3v

C4v

C6v

Cnh

C1h

C2h

C3h

C4h

C6h

Dn

D1=C2

D2

D3

D4

D6

Dnh

D1h=C2v

D2h

D3h

D4h

D6h

Dnd

D1d=C2h

D2d

D3d

D4d

D6d

S2n

S2

S4

S6

S8

S12

D4d and D6d are actually forbidden because they contain improper rotations with n=8 and 12 respectively. The 27 point groups in the table plus TTdThO and Oh constitute 32 crystallographic point groups.

[Edit]Hermann–Mauguin notation

Subgroup relations of the 32 crystallographic point groups (rows represent group orders from bottom to top as: 1,2,3,4,6,8,12,16,24, and 48.

Main article: Hermann–Mauguin notation

An abbreviated form of the Hermann–Mauguin notation commonly used for space groups also serves to describe crystallographic point groups. Group names are

1

1

2

2m

222

m

mm2

mmm

3

3

32

3m

3m

4

4

4m

422

4mm

42m

4mmm

6

6

6m

622

6mm

62m

6mmm

23

m3

432

43m

m3m

[Edit]The correspondence between different notations

Crystal family

Crystal system

Hermann-Mauguin (full symbol)

Hermann-Mauguin (short symbol)

Shubnikov[1]

Schoenflies

Orbifold

Coxeter

Order

Triclinic

1

1

C1

11

[ ]+

1

1

1

Ci = S2

x

[2+,2+]

2

Monoclinic

2

2

C2

22

[2]+

2

m

m

Cs = C1h

*

[ ]

2

2/m

C2h

2*

[2,2+]

4

Orthorhombic

222

222

D2 = V

222

[2,2]+

4

mm2

mm2

C2v

*22

[2]

4

mmm

D2h

*222

[2,2]

8

Tetragonal

4

4

C4

44

[4]+

4

4

4

S4

2x

[2+,4+]

4

4/m

C4h

4*

[2,4+]

8

422

422

D4

422

[4,2]+

8

4mm

4mm

C4v

*44

[4]

8

42m

42m

D2d

2*2

[2+,4]

8

4/mmm

D4h

*422

[4,2]

16

Hexagonal

Trigonal

3

3

C3

33

[3]+

3

3

3

S6 = C3i

3x

[2+,6+]

6

32

32

D3

322

[3,2]+

6

3m

3m

C3v

*33

[3]

6

3

3m

D3d

2*3

[2+,6]

12

Hexagonal

6

6

C6

66

[6]+

6

6

6

C3h

3*

[2,3+]

6

6/m

C6h

6*

[2,6+]

12

622

622

D6

622

[6,2]+

12

6mm

6mm

C6v

*66

[6]

12

6m2

6m2

D3h

*322

[3,2]

12

6/mmm

D6h

*622

[6,2]

24

Cubic

23

23

T

332

[3,3]+

12

3

m3

Th

3*2

[3+,4]

24

432

432

O

432

[4,3]+

24

43m

43m

Td

*332

[3,3]

24

3

m3m

Oh

*432

[4,3]

48

Crystal System

Crystal Class

Symmetry

Name of Class

Triclinic

1

none

Pedial

 

i

Pinacoidal

Monoclinic

2

1A2

Sphenoidal

m

1m

Domatic

2/m

i, 1A2, 1m

Prismatic

Orthorhombic

222

3A2

Rhombic-disphenoidal

mm2 (2mm)

1A2, 2m

Rhombic-pyramidal

2/m2/m2/m

i, 3A2, 3m

Rhombic-dipyramidal

Tetragonal

4

1A4

Tetragonal- Pyramidal

 

4

Tetragonal-disphenoidal

4/m

i, 1A4, 1m

Tetragonal-dipyramidal

422

1A4, 4A2

Tetragonal-trapezohedral

4mm

1A4, 4m

Ditetragonal-pyramidal

2m

14, 2A2, 2m

Tetragonal-scalenohedral

4/m2/m2/m

i, 1A4, 4A2, 5m

Ditetragonal-dipyramidal

Hexagonal

3

1A3

Trigonal-pyramidal

 

33

Rhombohedral

32

1A3, 3A2

Trigonal-trapezohedral

3m

1A3, 3m

Ditrigonal-pyramidal

2/m

13, 3A2, 3m

Hexagonal-scalenohedral

6

1A6

Hexagonal-pyramidal

 

66

Trigonal-dipyramidal

6/m

i, 1A6, 1m

Hexagonal-dipyramidal

622

1A6, 6A2

Hexagonal-trapezohedral

6mm

1A6, 6m

Dihexagonal-pyramidal

m2

16, 3A2, 3m

Ditrigonal-dipyramidal

6/m2/m2/m

i, 1A6, 6A2, 7m

Dihexagonal-dipyramidal

Isometric

23

3A2, 4A3 

Tetaroidal

2/m

3A2, 3m, 4

Diploidal

432

3A4, 4A3, 6A2

Gyroidal

3m

34, 4A3, 6m

Hextetrahedral

4/m2/m

3A4, 43, 6A2, 9m

Hexoctahedral

http://www.tulane.edu/~sanelson/eens211/32crystalclass.htm

the 32 crystal classes are divided into 6 crystal systems.

1. The Triclinic System has only 1-fold or 1-fold rotoinversion axes.

2. The Monoclinic System has only mirror plane(s) or a single 2-fold axis.

3. The Orthorhombic System has only two fold axes or a 2-fold axis and

2 mirror planes.

4. The Tetragonal System has either a single 4-fold or 4-fold

rotoinversion axis.

5. The Hexagonal System has no 4-fold axes, but has at least 1 6-fold

or 3-fold axis.

6. The Isometric System has either 4 3-fold axes or 4 3-fold rotoinversion

axes.

The Wilson cycle begins in Stage A with a stable continental craton. A hot spot (not present in the drawings) rises up under the craton, heating it, causing it to swell upward, stretch and thin like taffy, crack, and finally split into two pieces. This process not only splits a continent in two it also creates a new divergent plate boundary.      Stage B - the one continent has been separated into two continents, east and west, and a new ocean basin (the Ophiolite Suite) is generated between them. The ocean basin in this stage is comparable to the Red Sea today. As the ocean basin widens the stretched and thinned edges where the two continents used to be joined cool, become denser, and sink below sea level. Wedges of divergent continental margins sediments accumulate on both new continental edges.      Stage C - the ocean basin widens, sometimes to thousands of miles; this is comparable to the Atlantic ocean today. As long as the ocean basin is opening we are still in the opening phase of the Wilson cycle.     Stage D - the closing phase of the Wilson Cycle begins when a subduction zone (new convergent plate boundary) forms. The subduction zone may form anywhere in the ocean basin, and may face in any direction. In this model we take the simplest situation; a subduction zone developing under the edge of one continent. Once the subduction zone is active the ocean basin is doomed; it will all eventually subduct and disappear. These are remnant ocean basins.      Stage E - most of the remnant ocean basin has subducted and the two continents are about to collide. Subduction under the edge of a continent has a lot of results. Deep in the subduction zone igneous magma is generated and rises to the surface to form volcanoes, that build into a cordilleran mountain range (e.g. the Cascade mountains of Washington, Oregon, and northern California.) Also, a lot of metamorphism occurs and folding and faulting.     Stage F - the two continents, separated in Stages A and B now collide. The remnant ocean basin is completely subducted. Technically the closing phase of the Wilson cycle is over. Because the subduction zone acts as a ramp the continent with the subduction zone (a hinterland) slides up over the edge of the continent without it (a foreland).     Stage G - once the collision has occurred the only thing left for the mountain to do is erode down to sea level - a peneplain. The stage G drawing is a distortion, however. With the collision the continental thickness doubles, and since continental rock is light weight, both will rise as the mountain erodes, much like a boat rises when cargo is taken off of it. Thus, in reality, most of the hinterland continent will be eroded away, and the foreland continent will eventually get back to the earth's surface again.

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