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Новые достижения в химии и химической технологии растительного сырья. Материалы II всероссийской конференции [2005]

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N

 

 

 

 

 

 

 

 

 

CH2 N +

 

 

 

 

 

 

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O

 

 

O

C O

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68%

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258

 

 

NH2OH HCl

 

TsCl

 

 

 

O

O

"#$#%#&

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NC

 

 

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I

HON

II

 

III

 

 

 

 

 

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CH3I

 

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O

HOOC

H3!OOC

 

H3!OOC

 

 

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RSNa

O

H2O2, 30%

 

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H3!OOC

 

H3!OOC

 

 

 

RS

VII a-j

RS

VIII a-j

 

 

 

 

 

 

 

 

O

 

 

 

 

 

 

N

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R = C2H5- (a), C4H9- (b), C6H5- (c), C6H5CH2- (d), HOC2H4- (e),

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C

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H COOC2H5

 

 

 

 

 

 

45%

 

 

 

 

 

 

 

 

%#& : '$()& = 1 : 1.5

 

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1

 

 

 

 

 

 

 

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24

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25

R 2

HO

 

R1

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3. R1

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B" 6."1"5 %4.)*.) [10] 6 34()!.6) -3!.14/)*.4 +!%"&:9').!, +9"- %1"%4*"& +&+ 4;)."*. K)&:*$8 -3!.143. 46."1 *) 1492)&,). *4 3+!&'C + *)8.14&:*'C (4!.+, 343 -." "%+!4*" 6 %4.)*.47 [2, 9], 4 6!C !'55' )/" 3"5%"*)*."6 %1"!." *49$64). «!5)!:C .1+.)1%)*"6$7 3+!&".». E146- *)*+) 71"54."/1455 B=LM +9 %4.)*.*$7 "%+!4*+8 [2, 10] *)6"95"0- *", %"!3"&:3' *4 %)16"8 +9 *+7 *) %1+6)2)*4 *4(4&:*4, (4!.: 71"54."- /1455$ c %+345+ 14!.6"1+5$7 6 +9"%1"%4*"&) %"&,1*$7 3"5%"*)*."6 -3!.143.4 *)+96)!.*"8 7+5+()!3"8 %1+1"2$.

263

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1.!"#$%# &2025976 ('())*+). ,$-./(0 1.2., 3(4(#56*% 7.8., '"49.6*% 1.7., :$0;(0 <.7. * 9/. 1991.

2.!"#$%# &2108803 ('())*+). '"49.6*% 1.7., =/.6"%(0 7.>., 34*?(0 1.!., :.@*% 7.A., ,$-./(0 1.2. 1997.

3.!"#$%# &2108107 ('())*+). '"49.6*% 1.7., =/.6"%(0 7.>., 34*?(0 1.!., :.@*% 7.A., ,$-./(0 1.2. 1997.

4.B"C*#" * -"/"%#*% /")#$%*D. 1995. &5. < 26–47.

5.<E*)(- E$)#*;*9(0 * "6/(F*?*-"#(0, /"G/$H$%%5F - E/*?$%$%*I %" #$/- /*#(/** '())*D)-(D J$9$/";** (!/*4(K$%*$ - K./%"4. «B"C*#" * -"/"%-

#*% /")#$%*D»), 2., 2001. <. 251– 257.

6.L"? K$, 2002. <. 283– 285.

7.L"? K$, 2003. <. 314–317.

8.L"? K$, 2004. <. 322–326.

9.!"#$%# &2151139 ('())*+). / M7M «NOP7». 1999.

10.!"#$%# &2179393 ('())*+). / O(-#$0 1.J. 2000.

()*)!+*+,-.()/ *0)1.2304)5+/ )!()!3+637 A1)8)9+.) + *)8)()

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264

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(+4'.'2 60–70% [1, 2]:

N

CN

O2,NH3

H

N

t, 5#

1

N

 

 

3

N

CH3

N

2

6!1%'7"8!19 #$1!*:'$21;"9 (#'$'7' ,' *'./$<1!"= 1%&1%'".1 /<'(!"&1 %-,"!"!1 ( ,$"*-#*#("" '&*".!+4 (1!1.")-#"#1!'(+4 &1- #1%"01#'$'( ,$"('."# & !"#$"%- %-,"!"!'(') &"*%'#+ (5) * (+4'.'2

70–77%:

 

CH2OH

 

 

CN

 

 

 

 

 

 

 

O2,NH3

N

t, 5#

N

 

4

 

5

 

>"#$"% 9(%9/#*9 &%=8/(+2 ,$'.-'2 ( *"!#/0/ $10%"8!+4 ,$'- "0('.!+4 ?#') &"*%'#+, '@%1.1=A"4 (+$1</!!') :"0"'%'7"8/*&') 1"(!'*#B=, ( ,/$(-= '8/$/.B 1!1%B7/#"8/*&') [3].

C ;/%B= ,'%-8/!"9 !'(+4 :"0"'%'7"8/*&" 1"(!+4 (/A/*#( !1 '*!'(/ ,"$"."!'(+4 1%&1%'".'( !12" "**%/.'(1!' "4 ?%/$'&1#1%"- #"8/*&'/ 7".$"$'(1!"/ ( ,$"*-#*#("" *&/%/#!'7' !"&/%9, ,$'2'#"$'- (1!!'7' 2/#1%%12" V-) ,'.7$-,,+ D/$"'."8/*&') *"*#/2+.

E ?#"4 -*%'("94 ?%/$'&1#1%"#"8/*&'/ ('**#1!'(%/!"/ 1!1@10"!1 " !"&'#"!1 ,$'#/&1/# *#-,/!81#', 8/$/0 '@$10'(1!"/ ."7".$'-, #/#$1-

265

!"#$%- ", &'(%&)*, !)(+'!"#$%,$%"-.%#&%!%, ,%#%/&% 0%12, ('( 30% ,$%- "+4%#"0 ,$" !"#$"$%.'&"" ,"$"#"&' [4]:

NH

H2

NH

 

NH

NH

 

 

NH

N

 

N

NH

 

 

 

 

16

5$" 30%1 "- '&'/'-"&' (1) /67 ,%728)& l-!,9!-#",",)$"#"7 (6), ' "- &"(%0"&' (2) 3-,",)$"#"&%-2!-N-1)0"7,"$$%7"#"& !)(+'!"#$%&"(%- 0"& (7), ,$)#+0'.7:;<"= +%/%= +1)+> #.24 #"'+0)$)%"-%1)$%. 2'S,3R-

(8) " 2'S,3S- (9) , (%0%$6) 1%!20 /60> $'-#)7)&6 &' (%7%&() + %/$'<)&- &%= ?'-%= [5]:

 

 

H

 

 

H

 

 

H2

N

+

N

 

 

N

 

 

CH3

CH3

HN

CH3

NH

 

NH

2

8

9

 

 

 

@+0'&%.7)&%, 80% &' +%#)$A'&") +0)$)%"-%1)$%. . ,$%#2(0'4 !"#- $"$%.'&": .7":;0 0", ,$"1)&:)1%!% ('0'7"-'0%$' " 2+7%.": ,$%.)#)- &": .%++0'&%.7)&":. B'(, )+7" ,$" ('0'7"0"8)+(%1 !"#$"$%.'&"" 30% +%%0&%C)&") +%+0'.7:)0 3 : 1 [6], ,$" 37)(0$%('7"0"8)+(%1 .%++0'&%.- 7)&"" &' +()7)0&%1 &"()7) – 5,1 : 1, 0% ,$" !"#$"$%.'&"" &' ,$%1%0"- $%.'&&%1 .'&'#")1 +()7)0&%1 &"()7).%1 (%&0'(0) – 26 : 1.

D64%# !)(+'!"#$%&"(%0"&' . ,$%*)++) 37)(0$%('0'7"0"8)+(%!%

.%++0'&%.7)&": 67–72%, ' l-!,9!-#",",)$"#"7' 83–88%, 80% -&'8"- 0)7>&% .6C) +2<)+0.2;<"4 ( &'+0%:<)12 .$)1)&" 1)0%#%. +"&0)-' 30"4 +%)#"&)&"= [7, 8]. E/' (%&)8&64 ,$%#2(0' (6) " (7) !"#$"$%.'&": ,"$"#"&%.64 '7('7%"#%. . &)+(%7>(% $'- 1)&)) 0%(+"8&6 ,% +$'&)- &"; + "+4%#&61" '7('7%"#'1".

D-'"1%#)=+0.")1 +%)#"&)&"= (7) " (6) + '&!"#$"#'1" #"('$/%&%-

.64 ("+7%0 +"&0)-"$%.'&6 #"'1"#%("+7%06 (10) " '1"#%#"("+7%06 (11):

266

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