Новые достижения в химии и химической технологии растительного сырья. Материалы II всероссийской конференции [2005]
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2.H'=*# I.I. J3/3+%-93)3" 6%!3)*#%0. K. 1968. 536 4.
3.I/'#%0 L.D., @,#%0 I.L., M7%!*$4+'" I.L. N3)3" (#*0*43$8 3 43$2*231*- 4+39 6%!3)*#%0. ;O7., 1999. 628 4.
4.A!*$+%0' P.D. ;2#,+2,#' 3 #*'+53%$$'" 46%4%7$%42< 5*!!:!%/8. F., 1976. 368 4.
5.O'6+%0 ;.O., J'&$7*#= Q.R. L/'3)%(*&4203* 5*!!:!%/8 3 5*!!:!%/$89 )'2*#3'!%0 4 0%(%&. K., 1976. 232 4.
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)3" (#*0*43$8. 1980. G5. ;. 12–15.
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;. 72–80.
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11.O*2#%6'0!%04+3& B.I., A%2*!<$3+%0' P.U. J*$%)*$%!%=31*4+'" )%(*!< 2%$+%=% 42#%*$3" $'230$%& 5*!!:!%/8 ($' %4$%0'$33 344!*(%0'$3& =*2*#%- =*$$%& 3 =%)%=*$$%& (*42#,+533) // N3)3" (#*0*43$8. 1984. G6. ;. 23–35.
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